
FAQ’S
- What is Cyanoacrylate (CA) and how does it work?
- What is the shelf life of CA?
- What is the best way to keep CA fresh?
- Why do CA fumes burn my nose / eyes and make my eyes
water?
- Why are there different viscosities of CA?
- What is flexible CA?
- What is the M100XF High Performance all about?
- What is Low Odor or Foam Friendly CA?
- How strong is CA?
- What does triple distilled mean? Is my CA pure?
- Where are cyanoacrylates made?
- Why does the nozzle on CA bottles always clog and how
can I keep them from clogging?
- What is blooming (or all that white stuff)?
- What is Accelerator?
- Does the use of Accelerator compromise the bond of CA?
- Why are some substrates more difficult to bond then
others?
- What is Debonder?
- What are threadlocks and how do they work?
- What is retaining compound?
- Why are there different color threadlocks?
- Why do my different bottles of CA have slightly different colors or hues?
1. What is Cyanoacrylate (CA) and how does it work?
Cyanoacrylate (C5H5NO2) is an acrylic resin that cures almost
instantly. The only trigger, or catalyst, it requires are the hydroxyl
ions in water. Since almost any substrate you may want to glue will at least have trace
amounts of water on
it's surface CA will adhere to most anything.
When CA comes
into contact with water it undergoes a process called anionic
polymerization. In short this simply means
the CA molecules start linking
up into chains and these chains start whipping around to form a durable plastic
mesh. The glue thickens and hardens until the thrashing molecule strands can no
longer move.
2. What is the shelf life of CA?
If properly
made and packaged CA can last – 2+ years (Mercury has no time frame to its warranty).
The bottle that the CA is
packaged in is a vital link to the shelf life of CA. Mercury Chemist have
tested over 4500 different HDPE resins and there are only a handful that can
properly store CA and isolate the liquid inside from the moisture in the air.
The cap or closure is also very important to sealing out the water vapors that
exist in the air we breathe. The Mercury bottle uses proprietary resins in the
molding of the bottle and has a highly engineered triple seal closure to keep
moisture out and the product fresh. This is another reason why Mercury is the
only company that offers an unconditional warranty on their products.
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3. What is the best way to keep CA fresh?
The handling of
the product, once opened, is very important to the life span of the product. Always
keep the cap on when not in use, keep the nozzle clean from excess glue and
contaminants, keep the CA bottle away from accelerators, and store the sealed
bottle in a cool dry place.
Storing CA in
the refrigerator, in an un-opened container, will keep the product fresh for a
long time. Do not freeze CA; 40degrees F is an ideal temperature. Once you
open the bottle do not put the bottle in and out of the refrigerator as this
will introduce condensation to the inside of the bottle which will react with
the CA and it will start to set up.
4. Why do CA fumes burn my nose / eyes and make my eyes
water?
The fumes that you see coming from a glue joint is
from the heat that is generated during the anionic polymerization process, the
fumes do carry the cyanoacrylate within them, therefore when they come into
contact with mucus membranes (such as the nose, throat or eyes) the
cyanoacrylate reacts with the moisture contained within these areas and cause a
burning sensation. This process is not harmful to the body but can be
irritating; in some people it can be extremely irritating. This is not an
allergic reaction although some people are sensitized to this.
To prevent
problems all you need to do is make sure you move air across the work surface
with a small fan. The CA vapors will dissipate very quickly into the air and
become saturated within the surrounding air. If you are one of the few people
that are very sensitive to the fumes you can use the low odor M100F or M1000F CA, which will not fume
and cause problems.
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5. Why are there different viscosities of CA?
CA comes in different viscosities so it can be used
for a variety of applications. All Mercury products have the scientific
viscosities rating right in the name. The thin (M5T) CA is 5 cps (cps stands
for centipoises which is a scientific measurement for viscosity. 1 cps would be
equivalent to water, which is a very fast wicking grade CA. To use this product
you would hold the 2 pieces together and apply a small amount of adhesive at
the joint, it will wick or suck into the joint and set within a couple of
seconds.
The medium (M300M) is 300 cps, which is great for
porous materials or anywhere you may need minor gap filling qualities. To use
this product you apply it to one of the surfaces you want to glue and put the 2
pieces together and hold for about 15 seconds. This product takes 15 to 30
seconds to bond so you do have a little time for positioning.
The thick (M1100G) is 1100 cps, which is used for
maximum gap filling or anytime you need working time for re-positioning or to
assure a good alignment between your parts. The working time of this product is
45 to 60 seconds.
6. What is flexible CA?
CA by its very nature is
extremely brittle and cures very hard. While this can be a very good attribute
there are circumstances where this can be a negative attribute. Take for
example high vibration or high stress areas, the CA can be fractured which
would compromise the joint in these areas. Several years ago the Mercury lab
formulated a process where we can add a very specialized rubber to the formula
giving the product the ability to resist vibration and movement. Mercury
M3500FX was born and gives this product the ability to be used in areas where
CA has never been used before, such as speaker construction or motor mounts.
If you attempted to shave a bead of
regular CA it would just powder up as you cut it. If you did this with Flexible
CA you would actually be able to shave pieces off of the bead without it
turning to powder.
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7. What is the M100XF High Performance all about?
M100XF
is the result of nearly 2 years of lab work by Mercury Chemist. This work has resulted in a formulation
that is among the fastest, strongest and highest quality ever available.
This product is from the Ethyl
family of CA with a few proprietary additives included to increase speed and
strength. M100XF is 100cps in viscosity but yet still has very good wetting out
qualities when applied to a joint, it will not wick into the joint but will
soak into to the joint and surrounding wood to make a very strong bond. M100XF
can be used by either applying to one surface before positioning or it can be
applied to the joint after the parts are positioned. With these properties
M100XF is a great adhesive for using over the existing joints in ARF aircraft
where a good once over is needed before the first flight.
Another strong attribute is it’s
low vapor properties, while it is not a low odor product like M100F or M1000F
we have noticed, during the many hours of testing, that M100XF does not produce
the same amount of vapors as the standard Ethyl grade CA.
One of the best uses for this
product is on poplar plywood, or as we know it Lite-ply. We have also found it
to work great when sheeting with balsa or working with any tough to bond
surfaces.
The reason this product works so good on the poplar plywood is due to the high alkaline content of poplar. Alkaline is a neutralizer to cyanoacrylate, which will prevent the product from reacting with the moisture in the wood; in this case an accelerator would be used to promote the curing process. The accelerator will cure the CA but with a more brittle joint, the very thing we want to avoid when gluing plywood.
Based on extensive testing this
product is a great choice for assembling the ARF type models. Because of the
extensive use of poplar plywood in these models most manufacturers use a PVA
(polyvinalacetate) type of glue. This glue is an air-drying adhesive that cures
by solvent evaporation. Simply put, when the water, that carries the adhesive
to the joint, evaporates the adhesive that has spread into the joints grain and
crevices dries and forms a flexible, mechanical bond. These types of products
are heavy, slow and do not posses the strength of CA.
With the excellent wet-out
capabilities of M100XF you can go over the joints on your new ARF and be
assured the glue joints are solid. Also you can use this product during the
many assembly and gluing steps required to complete the model.
8. What is Low Odor or Foam Friendly CA?
Low Odor CA is a modified CA that produces very low odor and blooming. This product works great if you are sensitive to the CA fumes or are working with foam. Standard CA will attack most foam while the modified low odor M100F and M1000F CA is very foam compatible. Of course you should always test the product on a small non-visible area of your project before using any products on foam. This product, by its chemistry, is not as surface insensitive as regular Mercury CA so an accelerator like the popular Mercury MH16 may be needed. Surface insensitive simply means it will require more hydroxy ions, or water than other products. Some substrates, such as foam, have very low water content so an accelerator like Mercury MH16 is recommended. remember to test all CA products prior o using and only use small amounts for the best results.
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9. How strong is CA?
CA is extremely strong, it is not unusual to see
tensile strengths upwards to 2 tons per square inch! If your old enough you may
remember a television commercial where a person is hung by his hard hat, which
has been glued to the crane with CA (Super Glue).
As strong as CA
is in tensile it is considerably weaker in shear or peel forces (These are
forces applied perpendicular to the bond line). This is why it is important to
understand what forces will be applied to the joint and what the products being
bonded can withstand. While CA is not near as strong in shear as it is in
tensile a glue joint is only as strong as the substrates being bonded, for
example, if you were to bond balsa wood the balsa wood will always break long
before the glue joint would fail, no matter what the forces are.
Given all the
products we presently use in the modeling industry today it is safe to say that
a high quality CA like mercury products will withstand any forces the
substrates can withstand. This is why Mercury products are so widely used
today, they are very fast, very strong and since it only takes small amounts to
do any job it is the lightest adhesive available.
10. What does triple distilled mean? Is my CA pure?
You may see advertisements stating, “Our CA is
Triple Distilled” To a scientist this simple means it is not pure and needs
work. To distill something is to use temperature to remove impurities. The
product being distilled is first heated to a temperature that converts it into
a gas and then it is passed through a condenser where it is quickly cooled to condense
it or bring it back to a liquid state. During the heating process, while it is
converting to a gas the impurities fall to the bottom of the reactor and are
left behind. The condensed liquid is now a purified version of what it started
out as.
Triple distilling is a bit of a misnomer, in the past it has been explained that
triple distilling means it is a better product, while technically this is
correct because it is considerably better than it was when it started, why did
it take 3 distillation processes to get it purified? The answer would be
because it wasn’t very pure after the initial processing. Just because you
triple distill the CA doesn’t mean it will be 3 times as pure, the first
distillation will remove the largest amount of impurities with it falling
exponentially after each distillation. If you start out with a product that is
95% pure, after the third distillation you will only be able to obtain about
97.5% to 98% purity.
Mercury
Adhesive products are not industrial remnants or leftovers (as are most current
CA products) and actually come out of the in house reactor at 98% to 98.4%
purity, before distilling. Then they go through a single distillation which
brings them into the mid to high 99% purity level. This high purity level is
another reason that Mercury can offer an unconditional 2-year warranty.
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11. Where are cyanoacrylates made?
There are only a handful of actual
manufacturers of Cyanoacrylate in the world. Manufacturing CA is a very
involved, complicated and expensive process. While it is true that there are
“re-packagers” of CA in the USA there is only one true manufacturer. Mercury
Adhesives products are specially formulated and manufactured in Alpharetta,
Georgia where over 2 tons per month are produced with in-house reactors. All
the other products sold in the hobby market are made overseas and are some
times industrial remnants sold to the highest bidder and then shipped into the
US in bulk for re-packaging.
The problem associated with
shipping CA from overseas is simply the time lines it takes to produce the
products, package the products, and ship them to their final destination. Once
the products are made they typically sit in totes in a warehouse waiting to be
sold, this could be several months in un-controlled environments. Once product
is sold it is scheduled to be filled into bottles, typically taking another 30
days, then they are shipped to the US, which takes a minimum of 8 weeks on the
water (which by the way is the worst environment for CA). Once they make port they
can sit anywhere from 2 to 4 more weeks clearing customs before being shipped
to the customer, again all in un-controlled environments. At this point the
products are put into another warehouse where they could sit for several more
months waiting to be shipped to the retailer who sells to the end user. By the
time the products reach the retail shelf they can be as much as 12 months old
or older. The only way to assure an acceptable shelf life to the consumer, who
purchases this product from the retailer is to over stabilize the product with
added chemicals which greatly reduces speed, strength and consistency of the
CA.
Since Mercury Adhesives are made in
Georgia these time lines are reduced dramatically. Being one of the largest
producers in the world fresh batches are being produced every day which means
that product never sits in totes for more than a few weeks and in most cases
product is made to order. By the time Mercury products reach the retailer it is
never more than 60 days old, this means Mercury can make a much higher quality
more aggressive product since we do not have to over stabilize our products to
deal with the long time lines getting product to the retail shelf. This is also
another reason why Mercury Adhesives is the only company to offer a 2-year
guarantee.
12. Why does the nozzle on CA bottles always clog and how
can I keep them from clogging?
The CA in the tip of the nozzle is
reacting with moisture in the small orifice and hardening. Typically once the
CA hardens the user will take a pin and stick it down into the nozzle to open
it up only to find it clogs up even quicker the next time. What happens is the
pin scratches the inside of the nozzle, which allows even more CA to stay in
the nozzle causing it to clog up quicker. This process will be repeated several
times until the nozzle is no longer able to be used and gets thrown away.
Some companies have claimed to have
a clog free nozzle, which in reality is only a very long nozzle that you keep
snipping the clogged end off until there is no nozzle left and still end up
throwing it away. Other companies simply sell you extra caps and nozzles so you
can replace them after they clog.
Mercury Adhesives has actually
engineered a nozzle that not only will not clog but has 3 different points of seal
to assure the product inside is kept fresh and away from moisture. This cap has
a blunt nose, stainless steel pin molded into the cap, which engages into the
orifice of the nozzle (not scratching the insides of the bottle) to keep the
orifice clean. Inside the tip is a calculated venturie shape, which pulls the
CA out of the tip and back into the bottle once the bottle is stood upright. On
the very tip of the nozzle is a tapered seat which engages with a tapered boss
in the cap creating compression on the tip of the nozzle keeping the nozzle
clean and the product inside fresh.
If the cap is replaced each time
the user is finished with the product the nozzle will never clog.
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13. What is blooming (or all this white stuff)?
The phenomenon known as
blooming is when the CA vapors leave a white haze behind after curing. This is
typically caused by a couple of things. Too much adhesive is used, too much
accelerator is used, high humidity environment, and improper ventilation around
the part while the CA cures.
If an excessive amount of CA
is used you will get excessive gassing during the cure process which will cause
blooming. If accelerator is used in excessive amounts it speeds the curing
process up so dramatically that you will get a large amount of gassing during
the curing process causing blooming. The excessive moisture associated with
high humidity acts just like using too much accelerator. Improper ventilation
during curing will allow the vapors to build up on the surface and cause
blooming.
Blooming is strictly a
cosmetic issue and has nothing to do with the quality of the bond, if blooming
cannot be tolerated at all than it is good to use a low odor product that will
not gas or bloom.
14. What is Accelerator?
The Mercury MH16 Accelerator
is a solvent that is used to speed up the cure of CA. It typically is one of
three base ingredients, Alcohol, Heptane, or Acetone. Alcohol is the least
aggressive and most substrate friendly product. Heptane is a very good all
purpose accelerator as far as speed and substrate compatibility goes. Acetone
is the most aggressive and least substrate compatible product. Most available
accelerators are either Acetone or Heptane.
Mercury uses a Heptane base with
proprietary additives to give us a nice blend between speed and aggressiveness.
Our accelerators are foam compatible as well.
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15. Does the use of Accelerator compromise the bond of CA?
Depending on the type of
accelerator and the amount of accelerator used yes accelerator can compromise
the bond. Typically accelerator shocks the CA into curing causing a more
brittle joint. In some case the CA can be shocked so violently that it will
actually foam up introducing air into the joint. Accelerator should never be
used with thin CA and there are times, if used properly (like making fillets or
filling gaps) it is perfectly acceptable to use accelerator. If accelerator is
used always use it sparingly.
Mercury Adhesives accelerator
has been formulated to be a bit less aggressive so as to not shock the CA but
simply speed up the set time needed. The most common use for accelerators is to
help with hard to bond substrates.
16. Why are some substrates more difficult to bond then
others?
Not all substrates are
created equally, some substrates, like foam have very low moisture content.
Some substrates like light-ply have high alkaline content.
Foam, with its low moisture content
can be very difficult to bond, often requiring the use of accelerator.
Light-ply, with its high alkaline
content, can be very difficult to bond because alkaline is a neutralizer to CA
which makes it very non-reactive. In the case of light-ply the use of an
accelerator or our M100XF High Performance CA can be used.
M100XF has been specifically
formulated to handle the high alkaline levels in some woods giving the same
speeds and strength without the use of accelerator.
Some plastics like polyolefin’s can
be very difficult to bond and may require a primer be used before applying the
CA.
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17. What is Debonder?
Mercury M68DB Debonder is a
solvent, typically acetone based that dissolves dried up CA. It can also be
used carefully to separate 2 parts glued together with CA.
18. What are threadlocks and how do they work?
Threadlocks are anaerobic
adhesives, this means that they cure in the presence of metals and the absence
of oxygen. To use threadlocks you simply apply them to the threads of a bolt
and tighten the bolt. Once the threadlock comes into contact with the metal
bolt and the oxygen is removed during the tightening process it will cure on
the threads and prevent the bolt from loosening.
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19. What is retaining compound?
Retaining compound is also an
anaerobic adhesive that is used to retain bearings in seats and gears on
shafts. Retaining compound is typically more aggressive than threadlocks and
usually sets up faster and requires heat to get the parts separated.
20. Why are there different color threadlocks?
The different color
threadlocks are for different applications.
The MTL222 purple is repositionable
and is used for small, fine threaded fasteners.
The MTL242 blue is a medium
strength, repositionable and is used for larger fasteners.
The MTL271 red is a strong,
permanent product, which is used wherever extra strength is needed. This
product does require heat to separate the parts.
The MRT09 green is retaining compound.
21. Why do my different bottles of CA have slightly different colors or hues? The slightly different colors and hues come from the stabilizer used in the manufacturing process. This chemical has a fairly wide color window (20aspa to 150aspa). Mercury typically sees around a 30aspa to 50aspa, which for the most part would be colorless, the spec or tolerance can go as high as 150aspa, which would still be in spec and be a slight amber color. UV light can also have an effect on the stabilizer, causing an oxidation of the stabilizer, which would increase the aspa spec for that particular bottle. Note that his color difference or oxidation of the stabilizer has no effect on the stability or the performance of the product. Mercury has performed accelerated and real time testing on all Mercury products to the point of actually exposing them to enough UV light to oxidize them to the point of turning brown with no loss in tensile strength, set times, or increase in viscosity.

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